Well considering it is in the system32 folder I get zero hits on a google/yahoo search, that in itself is suspect. I would expect there to be at least a few hits for items in the system32 folder.
The file system shield is the on-access (resident) scanner and this will scan any file when it is accessed before it is allowed to run, something (another file or registry key) on your system is trying to tun this and avast is stopping it.
When did this happen, e.g. close to boot-time or when you did something ?
What action did you choose on the detection 'Move to chest' is the default ?