Obviously I can't speak from experience as I personally haven't had one of these alerts and I use windows update, but on XP Pro. What scan was it that detected this, about 8 minutes after boot, as part of an on-demand scan (which one) or something else ?
Was the alert like the one in the image (click to enlarge), as it does mention allowing the submission, yet doesn't have any yes/no option I can see. If so there is an Advanced option, I don't know if that gives the option to submit the file or not as I haven't had one of these alerts.
The avast community function does report information on alerts, but I don't know if it would send the file or how much data.