It happens from time to time when I need to access a site that avast happens to think is infected, and the network shield stops me from accessing it. So I end up disabling it, and forgetting to re-enable it.
Anyway, long story short, how do I add a site to the "allow" list. Real time shields -> Web Shield -> Expert settings -> Exclusions adding to "URL's to exclude" noes nothing. Still the site get blocked.