With outbound mail scanning you are uploading the mail twice - firstly it's uploaded and cached in the internet mail provider, then it is analyzed, attachments unpacked, scanned for viruses and then it is continuing its way to the destination server.
From the mail client perspective it goes very quickly, than it stops for a while transferring 0 bytes/s, then again it goes very quickly (for the next email). That is why the speed measurement might get confused.
This process and the upload (even to localhost mail scanner) takes some time and may be visible when network speed are very high - but I would not expect a significant slowdown with speeds about 90 Kbytes/s. We can re-check it in the morning and see if we see such a slowdown.
Of course, sending large compressed file has its own overhead. The attachment needs to be uncompressed before scanning and for large files it really does take some time.