..Downloading of pdf's etc attachments seems to be blocked after scanning as before.
Try turning off intelligent stream scanning. Avast GUI->Settings->Active Protection. Click on the little cog in Webshield, untick the box for "Use intelligent stream scanning" then click on OK. After exiting Avast GUI it may pay to reboot.
From the help file:-
" When checked, files that are downloaded are scanned in real-time i.e. during the actual download process. The packets of data are scanned as soon as they arrive - and the next ones are downloaded only when the previous packets have been verified to be infection-free. If this feature is disabled, by unchecking the box, the whole file will be downloaded to a temporary folder first and then scanned.
Hardened Mode is only Moderate
I don't personally have hardened mode enabled at all.
In the moderate setting no files with poor reputation will be allowed to run. I'm not sure why this should affect a pdf attachment, but try turning off hardened mode anyhow and see whether it makes any difference.