With the free version of avast there is no license file (license.avastlic), just a registration key, that has to be renewed each year. So if that email with the registration key is more than a year old you will have to re-register - this can be done from the avastUI > Maintenance section. If it is less than a year old Scroll down to Offline registration - Insert the license key.
Given that you have had another AV installed and this has somehow impacted on your avast installation, it may be best to do a clean install of avast (see #### below). The latest avast version is 9.0.2011, see
http://forum.avast.com/index.php?topic=142936.0, so I would suggest you install that.
I don't know how you removed McAfee, but it would be worth running its removal tool:
Uninstall possible remnants of previously installed AVs see,
http://singularlabs.com/uninstallers/security-software/, this has a collection of manufactures removal tools, so that should remove any remnants, registry, etc.
- Also see an updated list of AV uninstallers from Malwarebytes MBAM forum -
http://forums.malwarebytes.org/index.php?showtopic=127580&pid=689747&st=0&#entry689747.
####
- Download the latest version of avast, 9.0.2011
http://files.avast.com/iavs9x/avast_free_antivirus_setup.exe and save it to your HDD, somewhere you can find it again (if you didn't save your last download). Use that when you reinstall.
- Download the avast! Uninstall Utility, avastclear.exe
find it here and save it to your HDD.
- 1. Now uninstall avast! - using add remove programs, if you can't do that (as appears to be the case) start from the next step, reboot.
- 2. run the avast! Uninstall Utility, it will request it be run from safe mode (and will handle the boot into safe mode), once complete reboot into normal mode.
- 3. install the latest version, reboot.
Note: save the copy of avastclear.exe so it can be reused as some users are reporting that after running it, it is self-deleting.