I've made it to a Windows load! Don't ask me how (hadn't got round to entering all those commands from your previous post) but I'm a long way further than I've been for a while.
Admittedly I'm still looking at a predominantly black screen at this precise moment...but I can see Core Temp has loaded, which only loads on Windows startup.
So...assuming I get to a point where I can actually access my drives in a Windows environment...and aside from frantically copying all the files I want to keep to other drives...would you recommend me doing anything else?
Turning off Avast maybe? Even uninstalling it?