Arround 2010, there were some rumors that Avast was working in porting its antivirus to Win64 plattform. Unfortunately this is not the case even with 2016 beta.
A feature that is available since years ago in other vendors such as Bitdefender, and others using its engine like Comodo.
To me it is a pitty, since according to my tests, there is a slight about 10% performance improvement with x64 as comparison to x86.