'Load Avast services only after loading other system services' - Avast tec suggested this too, seemed to work somewhat last time I tried but not this.
"That is a bit strange as the anti-rootkit scan previously didn't start until 8 minutes after boot. I don't know if that has changed."
Maybe it doesn't......on other computers that are not so slow to startup?
"It may well be best to start your own new topic where it won't get buried in this already large topic. Collate what you have done here and we can try a different approach. There are some analysis tools that can check for anything untoward that may be hurting boot times."
I appreciate the offer to help......I have an old Dell desktop, I'm sure I would be told I need a new one.

What made me think it's Avast related is boot time being fast without it.......but then could be a case of when new technology meets old. Can low ram affect this? Please don't ask how much I have, you'd laugh and be amazed that my computer works at all with it.

I've bought some compatible memory, but need to pluck up the courage to install it, never worked inside a computer before.