Inside the C:\Programmi\Alwil Software\Avast5\defs folder, there's a small file called aswdefs.ini.
Can you please open it (e.g. in Notepad) and post its content here? (There's a value Latest=something inside - and I'd like to know if it refers to the latest folder you have on disk, or for example to the very first one - 19020600).
Also, could you please create a list of the files in the folders and attach it here? Just open a command line prompt (e.g. press Win+R and type cmd.exe into the box). Then copy&paste the following command to the command prompt:
dir /s "C:\Programmi\Alwil Software\Avast5\defs" > c:\windows\temp\aswlist.txt
After that, please attach the file (c:\windows\temp\aswlist.txt) here...
Thanks!