Unfortunately things change over time and this setting is no longer in the UI.
That said:
With a resident on-access antivirus like avast, the need for frequent on-demand scans is much depreciated. For the most part the on-demand scan is going to be scanning files that would be otherwise be dormant or inert. If they were active files then the on-access file system shield would be scanning them before being created, modified, opened or executed.
I used to have avast set to do a scheduled weekly Quick scan, set at a time and day that I know the computer will be on. But I have ceased this practice for some time now, based in the above.