1. The Web Shield gives but one option, abort the connection. This stops the infected item being downloaded, it doesn't drop your internet connection. You need do nothing other than click Abort Connection. Since this detection is of an item not on your system but the internet the option is simply don't download it 'abort connection.'
The Standard Shield which detects infected files on your HDD gives more options.
2. The boot time scan is different to the on-demand scan and when you select the schedule boot-time scan you get limited options.
3. see 2 above and image 3.
4. they do different jobs and you don't need to do a boot-time scan unless there is a problem that can't be dealt with in an on-demand scan, e.g. a file in use. It obviously won't be in use before windows starts.
5. because it is a quick scan, to give a report wouldn't be quick, you only get notification (by default) if something you scan is infected. You can enable reporting in Program Settings, Common, 'Show results of Explorer Extension.'
6. Having two resident scanners installed is not recommended as rather than provide twice the protection it can cause conflicts that could leave you more vulnerable.
7. No single AV can detect 100% you are also talking about viruses, there is adware, spyware, commonly trojans, etc. avast is primarily signature based but some of its generic signatures are designed to catch different variants of the same family group. You would be advised to have a multi-application approach. not two resident AV, but an anti-adware/spyware program.
Phew, that should keep you going, please limit the number of different questions other wise it gets complex and generates too many other question for people to follow.