I have exactely the same problem with my Windows XP home edition
I had to use the tool "UninstallUtility" to remove the program.
then i :
. Boot.
. Install again the last version.
. Boot.
And it does'nt work.
I removed it again.
I start windows in safe mode to use 'the administrator' account
and i install avast with this account and it does'nt work.
I tried many things but i have always the message :
ashAvast.exe - Erreur d'application
L'application n'a pas réussi à s'initialiser correctement (0xc0000005) ...
I'm French so i use a French version of XP
In english : Application Error - The application failed to initialize properly (0xc0000005).
What can we do
Thanks