It will likely be difficult to capture the problem as high disk usage at startup prevents practical user interaction at the time.
I have just had a look using Autoruns and have disabled a couple of (non Avast) tasks. I will see if there is any improvement.
PS: Autoruns lists Avast backup.exe as file not found. From reading, I believe this is a leftover from migrating from Win 8.1 to Win10, so is that startup item now defunct?