Thank you for the link to the Avast support section. I get as far as exporting the Mail Shield certificate. When I try to import it into Thunderbird, I get a box that says "This certificate is already installed as a certificate authority." That suggests to me that this is not the cause of all email being blocked.
Another thing that has not worked is going to the Avast shields Mail section and unchecking the boxes to Enable Mail Shield, Scan Inbound Emails, and Scan Outbound Emails.
The only thing that has worked is to temporarily turn off all of Avast's shields for 10 minutes when I want to check or send email. That's how I know that Avast is causing this.