I have XP as stated. Think I will have to wait for son-in-law again as he had problems getting into safe mode last time.
Well if this is the original release of XP then there have been 2 service packs since then and SP3 soon to be released. These service packs (along with Security Updates) close security vulnerabilities, they also fix bugs, etc. So if you really have the original XP it is way out of date and I don't know if there is a possibility that one of the old files that may not have had a bug fix applied could possibly have an effect.
So it is important to report the exact version and ensure that your OS is fully up to date to close any security holes.
The C0000005 error related to the anti-rootkit module and wouldn't have crashed your system, I had similar errors in my system and I didn't even notice it for 5 days as there was no impact on either the OS or the remainder of avast.
So I wouldn't recommend using system restore (I'm not a fan of it) as it can have effects that are totally unexpected, not to mention is isn't 100% reliable. I would say the clean reinstall with the steps you mentioned and using the uninstall utility also would probably be best.