Every once in a while I'll get those DCom warnings from the Network Shield too. One day I got them all day, always from the same address, which DNSStuff ID'd as Rogers Telecom. When I finally got through to their customer service to register a complaint (no mean feat, since I'm not a customer except for cable TV), they said the addy was commercial not residential, and I should have my ISP's tech people get in touch with theirs. So at that point I gave up.
I use Comodo myself, and tried blocking that addy with no success. So I think you can only be grateful that the avast network shield is (or seems to be) successfully blocking those things.