OK, I got figured out. I had the first Heuristic tab checked "Mark it subject field", now I checked "Let it be delivered" option.
I bet the problem was the suspicious *.exe attached file.
No exe. attached file, just the web link and the email attachment was a Microsft Word file.
Anyway, DavidR thank you very for all your help, I really appreciate it. My wife again forwarded both message and no more suspicious warning. I'm glad that Avast is protecting me, better safe than sorry!