Hi...I am a recycled Teenager (over 60

I am having problems today in that I cannot send emails but I can receive. I decided to do a scan with Avast....unable to do so.
The "start" button is greyed out.
Is there anyone who can point me in the direction as to what I have to do. I am not technically minded but I managed to muddle along until I get a problem.
Any help much appreciated.