I have downloaded and installed a k-lite codec pack. Is this something to worry about?
The folder C:\System volume information\_restore is used by Windows Restore feature.
If you disable, then enable again this feature, all restore points will be deleted and the detections will disappear.
So, shortly, you don't have to worry with that files.
avast can't scan files that are password protected, it doesn't know the password.
There are many legitimate reasons why a file was password protected. For instance, Lavasoft Ad-aware and SpyBot store their data in a password-protected ZIP archives (to prevent other similar tools from messing up with them). It's really nothing to worry about - it's normal.
In AdAware and S&D, when you fix/remove things it keeps backup/recovery information so you can restore anything that was mistakenly fixed/removed, etc. After a reasonable time your system has suffered no adverse effects, you can get rid of the older recovery/backup points. This should reduce the number of protected files.
Files that can't be scanned are just that, not an indication they are suspicious/infected, just unable to be scanned.