Correct me if I am wrong here, but given the last screen shot I guess that the account types are e-mail, not exchange. Therefore your exchange settings window - wherever you got it from - will have no effect.
1. Under Outlook 2010 go to File > Info > Account Settings > Account Settings ...
2. A window opens, the first tab, e-mail holds your current account, click Change ...
3. Untick SPA
4. Go to More Settings ... > Advanced tab
5. Untick "This server requires an encrypted connection (SSL)"