Does the speed change if you disable Web Shield or avast! entirely (restart browser after doing this).
Or, does it change if you uninstall avast! ? At such extreme speeds, it's quite likely that either ISP cannot deliver the promised 100Mbps or the host you're downloading from cannot keep up with your capability to download at that speed. It is however also possible that there is something conflictig inside avast!, resulting in a degraded performance of the internet.