sw,
I'm a little confused by your question.
- If you want to block your FW from Avast accessing anything, then yes, block avastsvc.exe...but this basically will prevent Avast from working.
- If you want to block another program (other than Avast) in your FW, then you would block it, but it has nothing to do with avastsvc.exe. Is there an example you can give me to help me understand your question better?