Well, a tool to help with your shutdown hangs has been suggested many times here, so I will stop repeating myself. On another note, FAT32 is insecure obsolete filesystem that should be avoided on system partitions.
As you see further up I have tested that tool.
No log entries at all.
Also have done a full cleanup (with the avast uninstall tools).
Reinstalled without changing any setting.
Still same problems (hang at shutdown with file shield active, repeat scanning etc).
Keep in mind that many XP system use FAT32 for the boot partition (and often the one with "Program Files").
So if avast! suddenly don't work with XP SP3 and FAT32 then they have a real problem.
Still want to help solving this, but how can I give more info?
I have reported all I can find, and tried all you have suggested.
Even uninstall other programs, but nothing has helped so far (except stopping "file shield")