First I want to mention that it is safer to move a found threat to the chest instead of deleting it, in case of a false positive. But when a threat is found in temporary files, just clean them with for example CCleaner. About the boot time scan, as it runs before Windows is booting it is easier to (re)move found threats. That said, I have no idea when ( or maybe always ? ) it is recommended by Avast!
Greetz, Red.