That will be sf.bin, the emulation engine for avast.
It is used to emulate code to see what it does, and if that code comes from the internet, i.e. avast is checking code on a website, then it will need firewall permissions.
Not exactly sure why there would be so many entries other than the fact that sf.bin changes with every virus database update (hence it's location) so ZA may see this as a new entry...