OK, test complete, this is related to the avast anti-rootkit scan.
Deleted old sig*.tmp files, stopped the anti-rootkit scan on system startup, image1. Rebooted and boot started at roughly 12:50 to 12:51, WGAErrLog.txt Date modified time is now 22/10/11 12:50. So I wait well over 8 minutes 13 in fact and check the c:\windows\temp folder and no new sig*.tmp files, image2.
So something has changed or broken in the anti-rootkit scan. Why this anti-rootkit scan function doesn't send the files to the avast temp folder c:\windows\temp\_avast_ folder; or if sending to a different folder why it doesn't clean up after it has completed the scan as the other avast scans do I don't know.
Since as has been reported this appears to have started on or about the 18th October 2011, what changed or broke in the anti-rootkit scan at that time.
What to do: I wouldn't disable the anti-rootkit scan too valuable a resource. I would recommend you do as I do as part of my regular weekly system maintenance and that is to run CCleaner to clean temp files. This tool isn't too aggressive so it shouldn't dispose of temp files that may be in use.