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If you deny a program to run, it's blocked, the file stays there and avast will keep it blocked until next reboot.
Search the specific file that was blocked, right click -> properties -> unblock.Try it and let us know what happens.If it doesn't work, please provide more info (OS, SP, x32/64, avast edition and version and so on).
What version of the Avast program you are using? Is it 6.0.1367? (Avast tray icon -> "About Avast")
That's why I keep asking where to look in Avast for anything that might have been accidentally blocked by me clicking on the Avast pop-up window that says something like " Allow | Don't Allow | Add to "list name." ( Not a direct quote of the syntax used by Avast)
How much RAM does the XP Pro SP3 system have Photoshop needs lots of RAM to run.