I've not heard of this were avast blocks emails, certainly not without displaying some warning window (virus, suspicious, heuristics, etc) saying why it would be blocked.
Check that messages aren't suppressed (silent).
If there are any warning messages then we might be more able to identify a problem.
You say the outbox is empty, did the email appeared in the sent items folder?
What is his OS?
What were his email account settings?