This is a boot-time scan, done before windows boots (not safe mode), this doesn't happen every time (but can be selected when required) and avast is the only AV that can do this (as far as I'm aware). It is a very handy tool for dealing with files that would be difficult to deal with if windows and they were running.
Not all files can be repaired, Trojans generally can't be repaired (either by the VRDB or avast virus cleaner), because the entire content of the file is malware, so it is either move to chest or delete, move to the chest being the best option (first do no harm). When a file is in the chest it can't do any harm and you can investigate the infected warning.
The VRDB only protects certain files, .exe, dll and other system files, it doesn't protect data files or all files, it is not a back-up program, so there are going to be many occasions where repair won't be an option. Since you won't have run this yet it can't offer any repair option.
Only true virus infection can be repaired, e.g. when a virus infects a file it adds a small part to it, provided that file is one that avast's VRDB would monitor and you have run the VRDB, then it may be possible to repair the file to its uninfected state.
However, for the most part so called viruses, trojans (adware/spyware/malware, etc.) can't be repaired because the complete content of the file is malicious.
The virus cleaner tool is designed to clean a small number of viruses and worm infections (listed on the page as you saw) and this is neither a virus or worm.
You have done the right thing, 'first do no harm' don't delete, send virus to the chest and investigate.
There is no rush to delete anything from the chest, a protected area where it can do no harm. Anything that you send to the chest you should leave there for a week or two. If after that time you have suffered no adverse effects from moving these to the chest, scan them again (inside the chest) and if they are still detected as viruses, delete them.
