You only need to initiate a boot-time scan if avast can't deal with a file e.g. it is in use and as such protected by windows. The fact that you have been able to send it to the chest (the first and safest option), means avast has been able to deal with it.
If on the other hand it couldn't do that then scheduling a boot-time scan would do the job and again you should opt to send to the chest when a detection is found.
Moving the file to the chest could potentially have the same effect as deletion in respect of the fact the file is no longer in the original location. The difference being you can always restore a file from the chest but you can't if you have chosen deletion.
You have XP SP3 (?) currently it is SP2, but SP3 is a beta release version, not something I would consider on a non-test PC.