You really would have to be gullible to fall for this and many other scams. How in hells bells would they know your email. Not to mention, in this case the Royal Mail is going to hell in a hand basket. Its level of service is getting worse not better so I couldn't see them even offering this service.
Whilst they have a tracking service they certainly don't have an email notification service, the sender would have to know your email, no doubt this would be a premium service which no doubt you the user would be paying for (so you should know and expect it). How would it even work if they had when they really haven't a clue when your parcel might arrive.
It doesn't take much rational thought to see through these scams.