Avast 5 free works perfectly fine ,without the behavioural module installed/enabled ,on 2 machines that i have XP SP 3/W7 64 bit.This module functions can be replaced by using a proper free firewall with XP ,firewalls that usually come with a (better) behavioural module by themselves .If you search a little the forum you will observe that this module doesnt do too much for the moment.Stay with it disabled ,nothing wrong will happen to you.The other shields work perfectly fine.
So keep that module disabled combine Avast 5 free with a good firewall and get over with it.
Aditionally ,if you want more start up speed you can disable the boot-up rootkit scanner via Settings ->Troubleshooting section.