DavidR, I understand that concern and would have thought the same thing, except when reformatting, reinstalling WinXP and software and a machine that had "locked up" as described, the first security measure I installed to the system was Avast! -- and that because I consider it the most important piece of rebuild after the OS -- then rebooted. And sure enough, the hang up occurred as described. So there was nothing else starting up with it other than Windows itself.
Tech, I'll make the attempt with Bootvis, first with my own machine, which is a mirror of the other. Not familiar with Bootvis, but I'll try if it will help.