- The avast5 tray icon is a part of the avastUI.exe process and there should be a startup entry for C:\Program Files\Alwil Software\Avast5\AvastUI.exe
First try a reboot if no change - Try a repair of avast. Add Remove programs, select 'avast! Anti-Virus,' click the Change/Remove button and scroll down to Repair, click next and follow. This has in the past resolved this out of sync issue between reported and actual VPS version.
Check the option in the Appearance tab of avast!5 Settings, Basic section.
What other security based software do you have that might block new startup entries, e.g. Spybot S&D (TeaTimer), AdAware (AdWatch), SpySweeper, Spyware Doctor (StartUpGuard or OnGuard), PrevX, WinPatrol, ProcessGuard, etc. ?
Ensure that any of these doesn't block the AvastUI.exe startup entry, Spybot is getting to be a real pain in the rear as there are many such conflicts relating to this in the forums. There are better anti-spy/malware applications that don't seen to have this issue, MBAM being one.
You could create your own startup shortcut in the startup folder (though not advised yet as we wouldn't be able to find the cause):
C:\Documents and Settings\YourUserName\Start Menu\Programs\Startup for C:\Program Files\Alwil Software\Avast5\AvastUI.exe /nogui (I believe the switch, /nogui just means don't open the GUI).
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The MBAM log detections appear to be good - Run MBAM again and this time when the scan is complete, all detections should have a check mark in the box to the left of the entry, leave them selected (or select if not selected). At the bottom of the window there is a button, Remove Selected, click that and the items will be removed.
Though I don't think that is what is blocking the avast icon.