OK- I gave it another session. Result - no real change. Details follow.
1. I tried updating to 6.0.1091 +/-. That went smoothly, but email sends still did not go through when WEB Shield was on. Did when off.
2. Uninstalled Avast and did a clean install. Went smooth, but same result: Web Shield stops email send, NOT Mail Shield.
I did NOT uninstall ZoneAlarm.. I think I'd rather have firewall protection than the web shield.
3. Thunderbird is v3.1.9 - current. Her accounts settings are per her ISP assistance. The server is not set for secure settings, SSL/TLS, but instead allows unsecure transmittal, or something similar to that. (Seems odd - but I left it as is.) She IS using port 80, not 25, to send - an alternative suggested by Earthnet, as Qwest, her DSL ISP, blocks 25 to prevent spam. Oddly, though, she doesn't have the "relay" in the server name as lit. suggests should be there, but as I have said the emails DO SEND when Web Shield is off.
4. In Avast, I set the SSL parameter to None - no change to email send. I then deleted the SSL account as directed. After reboot, it came back up - set to TSL, as it had been previously. But as I said, TBird is set to transmit unsecure, so I don't know why the TSL setting appears in Avast. Anyway, Web Shield still blocks email sends, and toggling back and forth alternatively result in corresponding success/failure in sending email.
So that is the status. Everything seems updated, but the Avast Web Shield blocks email sending. Turning it off results in successful email sends. So for now I just turned off Web Shield permanently, and things seem to be OK.
Thanks.
Rich